FYI Lithium and Lithium-ion are two DIFFERENT battery chemistries entirely. Lithium batteries are primary type cells, meaning not rechargeable (there are some secondary/rechargeable in work currently, but not common yet). You don't want to put water on a lithium battery due to the lithium metal. However, you typically only find lithium batteries in coin cells (think your watch/fob battery), so big fires are extremely unlikely.
Lithium-ion is a separate chemistry that is a secondary, or rechargeable, type cell. Because the lithium is bonded to a metal oxide (Co-O2, FePO4, NMCO, etc), the lithium is stable and water can be used.
In any case, it's difficult to use water for EVs because they're designed to be watertight, so you're trying to put out a self-sustaining fire/chemical reaction that's in a box in a box inside several dispersed cells.
This is not an electrical fire, as there's no sustained voltage. Once the cell fuse pops, you're only dealing with a single cell internal voltage of 4V (for lithium ion).
I've personally burned LFP cells in an inert nitrogen pressure vessel and they very much do burn. They're "better" than more reactive chemistries like NCA and NMC, but they do still burn (see story of burning teslas). That battery compartment likely has very little air in it, due to the large volume of gas vented during thermal runaway.
Let me know if you have any questions.