Help me decode the importance of EU Commission roles

In Denmark we usually have coalition governments, and when they are constituted you can see who's important and who's not from the ministries they are given.

Some ministries are more important - Finance, Justice, Foreign Affairs - and some are less important.

But which commission posts are the most important and powerful? I want to take a more active interest in EU politics, but that requires me to know what to look for :D